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Equilibrium is a word denoting a static condition, the absence of change In thermodynamics it means not only the absence of change but the absence of any tendency toward change on a macroscopic scale Thus a system at equilibrium exists under conditions such that no change in state can occur Since any tendency toward change is caused by a driving force of one kind or another, the absence of such a tendency indicates also the absence of any driving force Hence for a system at equilibrium all forces are in exact balance Whether a change actually occurs in a system not at equilibrium depends on resistance as well as on driving force Many systems undergo no measurable change even under the influence of large driving forces, because the resistance to change is very large Different kinds of driving forces tend to bring about different kinds of change For example, imbalance of mechanical forces such as pressure on a piston tend to cause energy transfer as work; temperature differences tend to cause the flow of heat; gradients in chemical potential tend to cause substances to be transferred from one phase to another At equilibrium all such forces are in balance In many applications of thermodynamics, chemical reactions are of no concern For example, a mixture of hydrogen and oxygen at ordinary conditions is not in chemical equilibrium, because of the large driving force for the formation of water However, if chemical reaction is not initiated, this system can exist in long-term thermal and mechanical equilibrium, and purely physical processes may be analyzed without regard to possible chemical reaction This is an example of the fact that systems existing at partial equilibrium are often amenable to thermodynamic analysis

'It can be modified using the Windows Form Designer. 'Do not modify it using the code editor. <System.Diagnostics.DebuggerStepThrough( )> _ Private Sub InitializeComponent( ) components = New System.ComponentModel.Container( ) Me.AutoScaleMode = _ System.Windows.Forms.AutoScaleMode.Font Me.Text = "Form1" End Sub End Class

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As indicated earlier, the state of a pure homogeneous fluid is fixed whenever two intensive thermodynamic properties are set at definite values In contrast, when two phases are in equilibrium, the state of the system is fixed when only a single property is specified For example, a mixture of steam and liquid water in equilibrium at 101325 kPa can exist only at 37315 K (100 C) It is impossible to change the temperature without also changing the pressure if vapor and liquid are to continue to exist in equilibrium For any system at equilibrium, the number of independent variables that must be arbitrarily fixed to establish its intensive state is given by the celebrated phase rule of J Willard

3 Hold down the SHIFT key and add another selection to the image The SHIFT key is a modifier that combines selections in the image

~ i b b s ; who deduced it by theoretical reasoning in 1875 It is presented here without proof in the form applicable to nonreacting systems:5

All the code that implements a form s behavior appears in the Form class in the System.Windows.Forms namespace. This project s initial form, Form1, inherits from that base form, receiving all of Form s functionality and default settings. Any custom design-time changes made to Form1 s user interface, such as adding child controls, are added to the InitializeComponent procedure automatically as you use Visual Studio. Check out the routine periodically to see how it changes. Most programs will have multiple forms. I suppose that .NET could select one of the forms at random to display when a program first runs. That would be fun and unpredictable. But it doesn t work that way. Instead, you indicate the starting form through the project s properties, via the Startup form field on the Application tab (see Figure 7-3). (The project properties window appears when you select the Project Properties menu command in Visual Studio, or when you double-click on the My Project item in the Solution Explorer.)

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4 Hold down the CTRL key and drag another rectangle in the image, this one intersecting at least part of one of the selections already in the image The CTRL key is a modifier that removes overlapping selections from the image You can use the CTRL key to take the edge off a rectangle or even to turn a selection into a donut by giving it a hole!

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